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A series of ferriostannylenes with differing terphenyl substituents

https://doi.org/10.1016/j.jorganchem.2023.122869

Phung, Alice C. ; Fettinger, James C. ; Power, Philip P. ( November 2023 , Journal of Organometallic Chemistry)

Free, publicly-accessible full text available November 1, 2024
Sn( ii )–carbon bond reactivity: radical generation and consumption via reactions of a stannylene with alkynes

https://doi.org/10.1039/D3CC04014C

Zou, Wenxing ; Mears, Kristian L. ; Fettinger, James C. ; Power, Philip P. ( November 2023 , Chemical Communications)

Thermal Sn–C cleavage in the diarylstannylene Sn(Ar^iPr4)₂(Ar^iPr4= C₆H₃-2,6-(C₆H₃-2,6-iPr₂)₂) was used to generate ˙Sn(Ar^iPr4) and ˙Ar^iPr4radicals for alkyne arylstannylation.

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Free, publicly-accessible full text available November 2, 2024
Correction to “Synthesis, Structure, and Spectroscopy of the Biscarboranyl Stannylenes (bc)Sn·THF and K 2 [(bc)Sn] 2 (bc = 1,1′( ortho -Biscarborane)) and Dibiscarboranyl Ethene (bc)CH═CH(bc)”

https://doi.org/10.1021/acs.organomet.3c00319

Phung, Alice C. ; Fettinger, James C. ; Power, Philip P. ( August 2023 , Organometallics)
Rearrangement of a Ge( ii ) aryloxide to yield a new Ge( ii ) oxo-cluster [Ge 6 (μ 3 -O) 4 (μ 2 -OC 6 H 2 -2,4,6-Cy 3 ) 4 ](NH 3 ) 0.5 : main group aryloxides of Ge( ii ), Sn( ii ), and Pb( ii ) [M(OC 6 H 2 -2,4,6-Cy 3 ) 2 ] 2 (Cy = cyclohexyl)

https://doi.org/10.1039/D3DT00906H

McLoughlin, Connor P. ; Kaseman, Derrick C. ; Fettinger, James C. ; Power, Philip P. ( July 2023 , Dalton Transactions)

Spontaneous Ge₆O₈cluster formation under ambient conditions using dispersion enhanced aryloxo ligands.

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Free, publicly-accessible full text available July 18, 2024
Disproportionation of Sn(II){CH(SiMe 3 ) 2 } 2 to ·Sn(III){CH(SiMe 3 ) 2 } 3 and ·Sn(I){CH(SiMe 3 ) 2 }: Characterization of the Sn(I) Product

https://doi.org/10.1039/d3cc01542d

Mears, Kristian ; Nguyen, Gia-Ann ; Ruiz, Bronson ; Zou, Wenxing ; Fettinger, James C ; Power, Philip P ( May 2023 , Chemical Communications)

Half a century since the photocatalytic disproportionation of Lappert's dialkyl stannylene SnR 2 , R = CH(SiMe 3 ) 2 (1) gave the persistent trivalent radical [·SnR 3 ], the characterization of the corresponding Sn(I) product, ·SnR is now described. It was isolated as the hexastannaprismane Sn 6 R 6 (2), from the reduction of 1 by the Mg(I)-reagent, Mg(BDI Dip ) 2 , (BDI = (DipNCMe) 2 CH, Dip + 2,6-diisopropylphenyl).
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Free, publicly-accessible full text available May 2, 2024
Clamshell Arrangements and Chirality in Cocrystals of C 70 with M II (octaethylporphyrin) (M = Co or Zn)

https://doi.org/10.1021/acs.cgd.2c01136

Baldauf, Lilia M. ; Fettinger, James C. ; Olmstead, Marilyn M. ; Ghiassi, Kamran B. ; Balch, Alan L. ( February 2023 , Crystal Growth & Design)

Full Text Available
Tuning the Intermediate Valence Behavior in the Zintl Compound Yb 14 ZnSb 11 by Incorporation of RE 3+ [Yb 14–x RE x ZnSb 11 (0.2 ≤ x ≤ 0.7), RE = Sc, Y, La, Lu and Gd]

https://doi.org/10.1021/acs.inorgchem.2c03817

Shang, Rongqing ; He, Allan ; Kunz Wille, Elizabeth L. ; Jo, Na Hyun ; Fettinger, James C. ; Canfield, Paul C. ; Kauzlarich, Susan M. ( February 2023 , Inorganic Chemistry)

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Investigation of relative stabilities of CPAM zirconium cycloalkylmethyl vs isomeric ω-alkenyl complexes: Crystal structures of the cyclobutylmethyl and cyclopentylmethyl complexes

https://doi.org/10.1016/j.poly.2022.116100

Epshteyn, Albert ; Zhang, Yonghui ; Fettinger, James C. ; Sita, Lawrence R. ( November 2022 , Polyhedron)

Full Text Available
Organocatalytic Asymmetric Synthesis of Si-Stereogenic Siloxanols

https://doi.org/10.1021/acscatal.3c03932

Dalton, Jacob J. ; Bernal Sánchez, Adilene ; Kelly, Austin T. ; Fettinger, James C. ; Franz, Annaliese K. ( January 2024 , ACS Catalysis)
Mn(II), Fe(II), and Co(II) Aryloxides: Steric and Dispersion Effects and the Thermal Rearrangement of a Cobalt Aryloxide to a Co(II) Semiquinone Complex

https://doi.org/10.1021/acs.inorgchem.3c00610

McLoughlin, Connor P. ; Fettinger, James C. ; Power, Philip P. ( June 2023 , Inorganic Chemistry)

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